Properties

PropertyWhy it mattersTypical science notes
Stable / aromatic CPersistence & CDRFused aromatic rings increase with T and time; H/C_org and O/C_org track condensation
Porosity / surface areaWater, nutrients, microbes, sorptionIncreases generally with higher pyrolysis T (then can decline at very high T)
pH / limingAcid soils, Al toxicityMany lignocellulosic biochars are alkaline
H/C_orgPersistence proxy; EBC/IBI qualityUpper limit 0.7 for “biochar”; lower ≈ more condensed
O/C_orgPersistence proxy (Spokas)Often <0.4 required; lower ≈ longer expected half-life
CEC / ash / nutrientsAgronomyAsh-rich chars supply minerals; CEC varies widely

Quality thresholds (standards)

  • EBC/IBI: H/C_org ≤ 0.7 (sometimes stricter for feed grades); O/C_org often ≤ 0.4
  • Molecular transitions with charring temperature: Keiluweit et al. (2010), Environ. Sci. Technol. DOI: 10.1021/es9031419
  • O/C as half-life predictor: Spokas (2010), Carbon Management DOI: 10.4155/cmt.10.32